A Stereospecific Synthesis of (±)-Abscisic Acid
نویسندگان
چکیده
منابع مشابه
Stereospecific synthesis of azetidine-cis-2,3-dicarboxylic acid.
Electrocyclic reaction product of 1-(methoxycarbonyl)-1,2-dihydropyridine was stereospecifically converted by RuO(4) oxidation into azetidine-cis-2,3-dicarboxylic acid.
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Short and high-yielding syntheses of enantiomerically pure (S)-(+) and (R)-(-)-abscisic acid are described. The syntheses proceed through key intermediates that preferentially recrystallise as single diastereoisomers for each enantiomer. This route allows the preparation of either enantiomer of abscisic acid in ca. 30% overall yield, and as demonstrated, gives access to an enantiomerically pure...
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ژورنال
عنوان ژورنال: Australian Journal of Chemistry
سال: 1992
ISSN: 0004-9425
DOI: 10.1071/ch9920179